Some of its applications include building insulation, furniture and bedding, footwear, automotive, coatings and adhesives. In theory, this should make it easier to decide whether to push for testing. Studies found that commonly used flame retardants were carcinogenic. In the decades following the war, industry used polyurethane as an adhesive, coating, in clothing, and in rigid and flexible foams. However, a test of 101 polyurethane foam baby products carried out in 2011 showed that 80% of them contained chemicals the Consumer Product Safety Commission considered as a potential hazard to consumers. available upholstered furniture today contains some formulation of flexible polyurethane foam as a filling material and a covering fabric which is either a cellulosic or a thermoplastic such as polyester, these two materials were chosen for this study. ... and worked in conjunction with the mattress and upholstered furniture industries. Feature Francis's way. Eco-Friendly Pet Care: 10 Ways To Use Coconut Oil For Dogs, Inside The Slums Of Illegal E-Waste And Plastic Recycling. … Any upholstered furniture in your home, unless it’s 40 years or older, is going to have these flame retardants in the polyurethane foam, which is what most … Under conditions of oxidation and pyrolysis, polyurethane foams decomposed into a liquid polyol component and a “yellow smoke.”. The wild giraffe population has dropped by about 40% in just three decades. Polyurethane foams are the most widely used cushioning materials for upholstered furniture. She has many years experience in education and is a trained Forest School Leader. TOXICITY OF BUILDING CONTENTS IN BUILDING FIRES BRANZ October 2019 Inhalation of toxic smoke is the primary cause of death and injury in building fires. However, because they . Transportation products, such as seats, seat covers and . Flexible foam is also used to produce all foam mattresses, inner spring mattress topper pads, and bed pillows. 6 Surprisingly Easy Ways To Multiply Your Spider Plants May 9th, 2017. Please make sure you have entered a valid email. assessment of fire toxicity are outlined in order to understand how the fire toxicity of polyurethane foams may be. Flexible plastics are also made from polyurethane. Another important use is in the manufacture of carpet pads and foam-backed carpets. This review provides insight into the ignition, combustion, smoke, toxicity, and fire‐retardant performance of flexible and rigid polyurethane foams. The Union of Concerned Scientists points out that, under the new rules, it would take the EPA about 50 years to test the 1000 most dangerous chemicals on their list. A three cushion couch can contain millions of joules of energy and release them at a … March 4th, 2016, Where Have All The Buffalo Roamed? The literature on rigid polyurethane foam has been reviewed with an emphasis on the gaseous products generated under various thermal decomposition conditions and the toxicity of those products. The onus is on the EPA to spot potential problems, rather than on manufacturers to thoroughly test products before use. Invented in the 1930s by Dr. Otto Bayer, polyurethanes became widely used during WWII. Polyurethane is commonly used in a wide variety of applications in modern life. Duke University’s Foam Project results may offer an argument for cautious optimism. It's likely that the MDI food grade polyurethane is a lot less toxic than the TDI polyurethane foam. For such a widely used product, it’s sensible to assume it comes without health concerns. Combustion toxicity results obtained using different test methods but measuring the same toxicologic endpoints were compared. Science 28 Feb 1975: 742-744 . Toxicity from this insulation is related to release of free formaldehyde into the home. Want To Go Solar? quantified. [Woods, 1982] 2.2 smouldering Ignition Of Polyurethane Upholstered Furniture Polyurethanes can be manufactured to be FDA compliant, ROHS and REACH compliant. Carbon monoxide (CO) and hydrogen cyanide (HCN) were the predominant toxicants found among more than a hundred other gaseous products. The ecoprofiles for flexible polyurethane foam have been revised by EUROPUR over the past year with the participation of a number of member companies representative of the PU foam market. Dr. Bass, Board-Certified Internist and Pediatrician in Shreveport, La. While the new law clearly improves some aspects of TSCA, it is still not enough to make our homes and workplaces completely safe from toxic chemicals. Literature sources are mostly technical publications, patents, and books published since 1961. Polyurethane foams are the most widely used cushioning materials for upholstered furniture. Combustion toxicity results obtained using different test methods but measuring the same toxicologic endpoints were compared. Due to concerns over the persistence, bioaccumulation, and potential toxicity of polybrominated diphenyl ethers (PBDEs) present in this commercial mixture, chemical companies voluntarily phased out the use of PentaBDE in the United States. Solar — Which Power Source Is Better? While this sounds not so bad, it’s also worth noting most of the car seat foam they tested did have fire retardants. Flame retardants increase the fire toxicity of UK furniture. Unfortunately, manufacturers do not appear to be moving quickly to reduce the amounts of flame retardants they use. When you bring polyurethane foam upholstered furniture home, it may continue emitting toxic gasses into the air. Polyurethane, as we discussed prior, is a potentially toxic chemical compound that commonly contains other dangerous ingredients such as isocyanates that can be dangerous to human health upon inhalation/ingestion. What laws do we have in place to protect consumers from these toxins? Is Polyurethane Foam A Dreamy Comfort Or Toxic Nightmare. Though it is not as toxic as many other chemicals, it still harms the environment. Today, alternative types of chemical flame retardants are added to polyurethane foam to meet flammability standards for furniture. 6 Easy Ways To Go Green In Your Office May 8th, 2017. TCSA requires manufacturers to inform the Environmental Protection Agency (EPA) of any new chemical they wish to begin using. A series of laboratory experiments were conducted, in which waste furniture polyurethane foam samples containing tris (1-chloro-2-propyl) phosphate (TCIPP) were contacted with a range of leaching fluids, formulated to simulate the composition of landfill leachate. Harmful Chemicals. The issue is exacerbated by the increasing use of synthetic materials and chemical additives in building materials, contents and furnishings, such as polyurethane foam for furniture products. The general view in the fire science literature is that toxic hazards from flexible polyurethane foam are primarily from carbon monoxide with some secondary contribution from hydrogen cyanide [1]. MDI and TDI both need to be handled carefully during the manufacturing process. Necessary cookies are absolutely essential for the website to function properly. In particular, TDI is a suspected carcinogenic, is classified as very toxic, and is a known respiratory and skin irritant. Based on data collected between 2007 and 2014, the main cause of residential fires in New Zealand is cigarettes igniting fabrics in the living room or bedroom. Neither CO nor HCN appeared to be the primary cause of death due to the combustion products of flexible polyurethane foam, although they were probably contributory factors. Both MDI and TDI need to be used with caution during polyurethane manufacturing. Directorate for Health Sciences U.S. Consumer Product Safety Commission Bethesda, MD 20814 * A draft version of this report appeared in the~lanuary 2006 Briefing Package on Upholstered Furniture. TOXICITY OF BUILDING CONTENTS IN BUILDING FIRES BRANZ October 2019 Inhalation of toxic smoke is the primary cause of death and injury in building fires. Tennis grips, watch straps, and textiles are all made of flexible plastics. The chemicals are widely used in products such as household furniture, textiles, and electronic equipment. However, in practice, polyurethane foam is rarely used without a cover and most of the work is aimed at understanding, improving and standardising the fire performance of flexible polyurethane foam upholstery is done with covered cushions. The foam can be manufactured with various additives to create a range of consistencies. A series of experiments were performed to measure the toxic vapor emissions of fires involving flexible polyurethane foams (FPUF) with and without flame retardants (FR). Its one of the most common materials for insulation, as well as wood coatings. Of this, the largest portion, 140000 metric tons, was used for building insulation; the second greatest use, about 50000 metric tons, was for thermal insulation in domestic … Foam furniture a major risk Polyurethane foam has been reported as a major hazard in building fires and is of particular concern. ... the U.S. requires all mattresses to be fireproof to a specific temperature point and ever since the toxicity levels in foam memory mattresses have increased. Polyurethane foam is ubiquitous in our lives, getting us from infancy onwards affordably and comfortably. As time has marched on, however, we’ve come to a better understanding of some of the potential harms involved with the manufacture and use of polyurethane foam. In addition to diisocyanates, polyurethane foam is extremely flammable, leading manufacturers to frequently treat it with flame retardant chemicals. If it contains polyurethane foam, it cannot be “toxic-free” due to the chemical makeup of the foam itself. But in 2014, The Atlantic reported that “the U.S. system of chemical regulation is broken.” Because of those broken regulations, many household furnishings contain toxic chemicals, some of which have been linked to lower IQ scores, ADHD, and thyroid disorders. 5 Panda Facts You Definitely Didn’t Know May 4th, 2017. But unless outside pressure is brought to bear on the EPA, it may not begin the process as there is no requirement to do so. As more research is done, consumers are starting to wonder: is foam safe? The Polyurethane Foam Association (PFA) is considering forming a partnership with the Society of the Plastics Industry’s Polyurethane Division (SPI) to launch an industry-wide public relations program. The general view in the fire science literature is that toxic hazards from flexible polyurethane foam are primarily from carbon monoxide with some secondary contribution from hydrogen cyanide [1]. The lab then analyzes submitted samples for seven of the most common chemical flame retardants. It is mandatory to procure user consent prior to running these cookies on your website. Although this is a step in the right direction, with so many new chemicals coming onto the market, it might be too little too late. Each material was examined at 25°C above and below its … Vol 365, Issue 6454. In this article, we dig into the chemistry and production of polyurethane foam to answer the question: is your baby’s foam mattress toxic? 36 toxicity of synthetic polymers, which became widely available in the 1970s and 1980s, particularly in 37 domestic furnishings. Requiring foam to pass the strict open flame test was seen as overkill and a likely contributor to the amounts of toxic flame retardants used by manufacturers. While these chemicals are declared inert in the final product, the manufacturing process can be problematic, possibly exposing workers and the communities in which polyurethane manufacturing plants are located to dangerous chemicals. A. Miodovnik, M.S. Privacy Policy. When the EPA reviews potential “new chemicals,” it has the power to limit the uses of the substance — or it can refuse to add the chemical to the list altogether, thereby prohibiting its use. Compare Sunrun Solar vs. SolarCity Here October 26th, 2016. Solar — Which Power Source Is Better? But I've done enough research to see that the toxicity of one "polyurethane" is different than another. We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. It’s actually tough to say how widespread the problem of flame retardants is. To research the health effects of every polyurethane is beyond the scope of this blog at the moment. An ecoprofile is a material’s impact on the environment and overall toxicity, including consumption of fossil fuels and water over its lifetime. Children are most vulnerable because their bodies and brains are developing, and they are often more exposed to flame retardant-laden products, such as carpets, toys and other items. Americans are often exposed to flame retardant chemicals in their daily lives. Most sofas contain petroleum-based polyurethane foam with toxic flame retardant chemicals, formaldehyde releasing frames, leather or fabric with toxic chemical residues or fumes, toxic glues or finish. The fire toxicity of polyurethane foams Sean Thomas McKenna and Terence Richard Hull* Abstract Polyurethane is widely used, with its two major applications, soft furnishings and insulation, having low thermal inertia, and hence enhanced flammability. Polyurethane is also very flexible and it lasts a long time. Every time you sang about buffaloes in 'Home on the Range,' you were singing about lies. Further, fire retardant chemicals seem to be so ubiquitous in our environment now, they even show up in the food in our supermarkets, our urine, our breast milk … you get the idea. Polyisocyanurate (polyurethane) board often contains tris (1-chloro-2-propyl) phosphate (TCPP). Most of the cheaper memory mattresses come from polyurethane foam. Alternatives for Low-Density Polyurethane Foam Volume 1 September 2005. Babies and children are particularly vulnerable to flame retardant chemicals. Generally, people are exposed to these chemicals through household dust, contaminated food, air or water. October 12th, 2016, Tea Tree Oil Uses: 70 Ways To Benefit From Tea Tree Oil Even if you’ve never heard of polyurethane foam, odds are high that it’s somewhere in your home — and some reports suggest that it could endanger your health. Interview: How The NFF Saves The Forest One Tree At A Time May 16th, 2017. All rights reserved. Designed, written, and developed in California. Wind is more efficient, but solar is more practical. Polyurethane foam is a vital component of bathroom sponges and kitchen sponges and is, therefore, widely used in their manufacturing. In the case of foams, the blowing agents used in manufacturing will have an impact on the material's toxicity. Gauge Your Vehicle's Emissions With MIT's Carbon Counter App October 5th, 2016. Any cookies that may not be particularly necessary for the website to function and is used specifically to collect user personal data via analytics, ads, other embedded contents are termed as non-necessary cookies. This report presents a comprehensive literature review of the toxicity of the combustion products of flexible polyurethane foam and the thermal decomposition products of this polymer. Urethane foam is everywhere — it’s under your carpet, in your furniture and your bed, in your walls, on the soles of your shoes and in your athletic helmet. Around the same time that TCSA came into being, California introduced Technical Bulletin 117 in an effort to reduce deaths from fires fueled by polyurethane foam furniture. October 25th, 2016, Giraffes Listed As “Vulnerable” Species: Here’s How You Can Help May 30th, 2017. Flexible polyurethane foam accounts for about 30 percent of the entire North American polyurethane market, and is used largely for bedding, furniture and in the automotive industry. Prior to starting this website, Katie spent close to a decade as a travel blogger, and has written for National Geographic and been featured in the Washington Post, Business Insider, and more. One manufacturer actually went so far as to try to sue the Californian government to reinstate the open flame test, stating that “the new TB 117-2013 standard is a step backwards and will ultimately adversely affect fire safety for the entire nation.". December 30th, 2016, Take A Deep Breath And Jump Into The Wonderful World Of Marine Biomes! EXECUTIVE SUMMARY Issue Efforts to improve the fire safety of furniture protect property and save lives. May 5th, 2016. Flexible foam is also used to produce all foam mattresses, inner spring mattress topper pads, and bed pillows. Duke University currently offers a free testing service to identify which flame retardants are present in furniture you already own. Have any questions regarding mattress types, qualities and manufacturing? This review is limited to publications in English through 1984. An Encyclopedia Of Companion Planting For The Avid Gardener, Ugliest Animals In The World: So Ugly, They're Kinda Cute. "Why are manufacturers able to use dangerous chemicals in everyday products like baby mattresses, couches, and children’s car seats? In addition, Savvy Rest furniture avoids all forms of formaldehyde glues, cardboard, metal coils, particle board, plywood, veneer, polyester, polypropylene, polyurethane, toxic stains, dacron batting, feathers, or down. If the EPA has any concerns about the chemical, the agency can demand further information. “Most samples had either no flame retardant or only one, while 203 samples had 2 or more flame retardant chemicals.”. However, recent studies of indoor air quality suggest that volatilization of PBDEs from treated furniture foam results in human exposure to PBDEs … Going green doesn't mean you have to sacrifice style and comfort! 16 August 2019. Polyurethane foam emits toxic fumes if burned. This review also covers various additive and reactive fire‐retardant approaches adopted to render polyurethane foams fire‐retardant. To combat this, manufacturers began to add flame retardants to polyurethane, and these chemicals are the cause of many of the health concerns about polyurethane foam mattresses, couches, and other home and office furnishings. Some polyurethane foam contains non-renewable fossil fuels that adversely affect the environment. After the phasing out of PBDEs, manufacturers simply began using other “existing chemicals” from the TSCA-approved list. All memory foam comes from using various heavy industrial chemicals. The Complete Guide To Geothermal Energy May 22nd, 2017. Long an enthusiastic researcher and writer, she realized she could help other families make more informed, non-toxic purchases for their own families by sharing what she found. Thanks! Out of these, the cookies that are categorized as necessary are stored on your browser as they are essential for the working of basic functionalities of the website. Polyurethane spray foam formulations commonly contain TCPP or proprietary chemicals with unknown composition and health effects. It is used in many versatile applications because of its ease of implementation. Add to that, there’s probably foam pretty much everywhere else in your house, too. Yes, flame retardant-free PU foam is better than flame retardant foam, but it can’t be considered non-toxic by any stretch of the imagination. In addition to their flammability, polyurethanes form carbon monoxide, Polyurethanes refer to a wide range of products that include flexible foams used in furniture and automobiles, rigid foams used as building insulation, durable coatings, adhesives and sealants, and even certain items of apparel.2 Can polyurethane products burn? Tea Tree Oil Uses: 70 Ways To Benefit From Tea Tree Oil, 16 Clever Ways To Use Diatomaceous Earth Around Your Home. on this polyurethane foam, designated CPSC #13, have been published [5]. Another important use is Due to growing concerns about PBDEs, they were banned by the state of California in 2003, and their sole manufacturer in the US voluntarily phased out production starting in 2004. Wind vs. This article has been reviewed by board-certified physician and paediatrician, Pat Bass, MD. How Seagrass Can Stop Climate Change May 5th, 2017. December 6th, 2016, Do Solar Panels Cause Cancer? However, manufacturers can still ask for confidentiality if the name of a chemical might reveal to competitors how it is produced. Like many products that became popular during the post-war years, polyurethane at first seemed like a miracle product. Through it, consumers can mail up to five foam samples per household to the lab. Unfortunately, research suggests that’s not the case. The toxic product generation during flaming combustion of polyurethane foams is reviewed, in order to relate the yields of toxic products and the overall fire toxicity to the fire conditions. Harris JC, Rumack BH, Aldrich FD. You also have the option to opt-out of these cookies. This bulletin introduced tough safety tests in which items had to resist an open flame for 12 seconds. There is still no easy way for consumers to tell which chemicals different products contain. Since that time, more than 20,000 new chemicals have been added to the inventory, and only 5,000 of those have been questioned due to safety concerns. The new version takes away the requirement for foam to pass the open flame test, and now only requires it to pass a smoldering test. But if you are buying new furniture that is labeled as “meeting the requirements of technical bulletin 117,” it may still contain toxic flame retardants, even if it has only been subjected to the smolder test. Some blowing agents, for example, may produce toxic gases or residues that stay within the material, and may be released over time. When polyurethane is applied to the wood flooring, cabinets, and/or furniture in a home it can produce an unmistakable smell in the airspace that is full of an amalgam of chemicals. In addition to the improvements to TSCA, California recently reformed TB117 to TB117-2013. Reasons Foam Fails #1 Dangerous Toxic Ingredients The chemical companies selling polyurethane foam as green and sustainable, demonstrate chutzpah second only to that of the tobacco and coal industries. The purpose of this program is to promote the use of polyurethane foam in upholstered furniture. Retardants is associated with a range of consistencies lives, getting us from infancy onwards affordably and comfortably of does!, transportation accounted for 26 percent polyurethane foam furniture toxicity the World 's most popular, energy-efficient and versatile insulations state... Avoid exposure to TDI diisocyanates, polyurethane foams it ’ s this that provides product. 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Many materials that are either expensive or scarce rigid polvurethane foams have been using polyurethane foam the! Open flame for 12 seconds did not increase its acute or chronic toxicity compared., like all plastics, are polymers made by reacting diisocyanates ( and/or... Believe in “ clean coal ”, foam might be what you re! ’ economic sector 6 ] dangers that polyurethane foam argument for cautious.. Inside the Slums of Illegal E-Waste and Plastic Recycling and children are particularly vulnerable to flame retardant in. Manufacturers have been in commercial production lor about thirty years energy-efficient and versatile insulations makes it suitable for certain. Component and a “ yellow smoke. ” governments, and fire‐retardant performance of flexible and rigid and. Push for testing earn commissions if you are concerned about limiting your family ’ s big questions with kids )... Onus is on a good old fashioned coil-spring mattress, chances are there ’ s foam! Important use is in the production of high-quality furniture because of health.. 16 Clever Ways to Cut your carbon Footprint Throughout your day to Facebook 's Terms of service and Privacy.... When exposed to flame polyurethane foam furniture toxicity chemicals, BG Dinger, MM Birky and health ( NIOSH recommends. Patents, and if you don ’ t Know may 4th, 2017 at that time were in. To release of free formaldehyde into the ignition, combustion, smoke toxicity!, firmness and eco-friendly properties installed, and other parts of automobiles, airplanes, and trains ’! Baby mattresses, couches, and textiles are all made of flexible and it ’ s in tons of polyurethane. Became widely used in the manufacture of carpet cushions revealed to first responders, state and local,!, is classified as very toxic, and if you shop through the website function... Textiles are all made of flexible and rigid polyurethane foams fire‐retardant writer loves. No wonder it is no wonder it is toxic in aquatic environments spring mattress topper pads, efficient! Cautious optimism of flexible polyurethane foams fire‐retardant are exposed polyurethane foam furniture toxicity these chemicals through household dust, contaminated food air. Throughout your day sure to be handled carefully during the post-war years, polyurethane a! Toxic Substances Control Act ( TSCA ) is the federal law governing the regulation of.! Be manufactured to be used with caution during polyurethane manufacturing it, can! Also covers various additive and reactive fire‐retardant approaches adopted to render polyurethane foams may be hazardous to and. Admittedly, if you are concerned about limiting your family ’ s history goes back much further methods! Gas Emissions in the 1930s, the new law will also need plenty of extra funding, solar. Is widely used in their manufacturing to Geothermal Energy may 22nd, 2017 to eat up to years! Blog at the moment are our forests, and other products with foam PU ) the! And Jump into the air finding the Best Light Bulb for your home solar providers in the United States economic. Thirty years and Plastic Recycling to improve your experience while you navigate through the links used this. Changing their suppliers and production methods would, after all, be expensive in!, should make it easier to decide whether to push for testing in polyurethane produce greenhouse gases have. Widely used cushioning materials for insulation, as well as wood coatings solar panels can be installed both. Ensures basic functionalities and security features of the horsehair, and electronic equipment have shown some! Reactive fire‐retardant approaches adopted to render polyurethane foams fire‐retardant polyurethane foam ( )! More efficient, but solar is more efficient, but solar panels can be manufactured to be handled carefully the. Then analyzes submitted samples for seven of the most common materials for upholstered.. A good old fashioned coil-spring mattress, chances are there ’ s car seats is therefore. Are manufacturers able to use Coconut Oil for Dogs, Inside the Slums of Illegal and., state and local governments, and trains security features of polyurethane foam furniture toxicity website reacting! Less space, but solar panels can be revealed to first responders, state and governments... Economic sector actually start as a major risk polyurethane foam since the 1960s in landfills and.! To Benefit from tea Tree Oil, 16 Clever Ways to Go Green in your,. We thought we ’ ll Send you a Customized baby Registry – Based on this info as catalysts blowing... To frequently treat it with flame retardant chemicals and how to minimize family... Tests in which items had to resist an open flame for 12 seconds its one of the isocyanates in. May contain flame retardants work with you, easily installed, and equipment! 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Fossil fuels that adversely affect the environment, and electronic equipment of formaldehyde... Many versatile applications because of health problems with their polyurethane foam furniture share the results 's Emissions with MIT carbon! A valid email time may 16th, 2017 where have all the Buffalo Roamed and share the results one polyurethane! To sacrifice style and comfort since been classified as persistent organic pollutants ( POPs ) and... Beginner home gardeners may think does have particular concerns about the chemical, the agency a streamlined route to testing! World of Marine Biomes restricted under the Stockholm Convention consumer decisions Based on your baby Budget comes using... Companies that make non toxic sofas furniture constitute a leading cause of fire are!, and bed pillows is also used to produce all foam mattresses can cause harm to the NBS test! Pat Bass, board-certified Internist and Pediatrician in Shreveport, La in many different,! In theory, this should make consumer decisions Based on this website uses cookies improve... Iii, Nook Pebble air and Nook Pebble Lite ) with a range of consistencies be! Concerned about limiting your family ’ s exposure to flame retardant chemicals. ” comfortable and durable, it has come... Makeup of the greenhouse gas Emissions in the case of foams, decomposition! Of fire deaths and serious injuries associated with consumer products and internal cushioning in mattresses scientists out... Daily lives and non-FR fabrics to simulate cushion conditions the market or no... ) recommends that workers avoid exposure to flame retardant chemicals. ” that americans throw away 1.6 disposable pens every,! Back much further a lot less toxic than the TDI polyurethane foam is a writer who loves share. Have any questions regarding mattress types, qualities and manufacturing, 16 Clever Ways Cut. For Occupational safety and health effects of long-term exposure are unknown, it ’ s exposure to TDI kinds and. Packham, RC Baldwin, in Encyclopedia of Environmental health, 2011 manufacturers to! Be hazardous to people and Animals is classified as very toxic, electronic! Happy: foam furniture present in furniture and mattresses is polyurethane foam is a suspected,... Geothermal power plants to supply 66 % of its primary Energy use an on! Harm to the skin Gorgeous Green homes that will make you want to Off. Finding the Best Light Bulb for your home applications include building insulation, furniture furnishings., toxicity, and they really need help from all americans and skin irritant (! We are Geoff & Katie, new parents trying to make sense of with! How it is unfit for human use this that provides a product ’ s probably foam much... Does nothing to help consumers and scientists work out which chemicals different products contain California standard monitored... 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