Bis 4-isocyanatophenyl methane 1-Isocyanato[ 4-isocyanatophenyl methyl]benzene 4,4′-Methylene diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI. 1The ingredient is the polymerized (cured) form of methylene-diphenyl-diisocyanate (MDI) resin in the raw composite panels used by Columbia for the production of PureBond assemblies. It may be toxic by ingestion, inhalation, or skin absorption. 0 Methylene diphenyldiisocyanate. Products include monomeric and polymeric methylene diphenyl isocyanate (MDI), toluene diisocyanate (TDI), specialized blends, modified MDI, and … 메틸렌 디페닐 디이소시아네이트(MDI, Methylene Diphenyl Diisocyanate)는 방향족 디이소시아네이트류 화학 물질이다. 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) White to light … Consequently, Millionate MT is suitable for the preparation of liner polymers by reaction with diols and diamines. 101 0 obj <>/Filter/FlateDecode/ID[<16B2F27BCE126B46B9EB2A6FD19D8AB1>]/Index[80 38]/Info 79 0 R/Length 96/Prev 135164/Root 81 0 R/Size 118/Type/XRef/W[1 2 1]>>stream EINECS 219-799-4. +;×f­®b¬76¼ŠŽñQÈÙ´Úø1'ß½.Û ÈbŸ˜­Ýn_w ¤„”UdÆÓÏ©€99+éwт1ØßHMðL¿.h& ‘Ìe®9WÍA³òtÁÞϤ8ªvĦÊödMÓ}Kf½óÌz"ÁÚóŠÙ¼ò,-øփH".‰X=МÊÌ?À¨ÜƒCÄØ´Ø]œ¶O˜˜±ÒýP The 4,4' isomer is most widely used, and is also known as 4,4'-diphenylmethane diisocyanate. Safety Data Sheet (SDS) 1. Chemsrc provides 2,2'-Methylenediphenyl diisocyanate(CAS#:2536-05-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Polymeric diphenylmethane diisocyanate 9016-87-9 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 TOXIC SUBSTANCES CONTROL ACT: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. SDS Number: 00047043508 SAP Number: 9700050112 Revision Date: 11/29/2018 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: ... 4,4’-Methylene diphenyl diisocyanate (MDI) 0.005 ppm TWA Methylene bisphenyl isocyanate (MDI) N.E. Current OSHA PEL: 0.2 mg/m 3 (0.02 ppm) CEILING 1989 OSHA PEL: Same as current PEL 1993-1994 ACGIH TLV: 0.051 mg/m 3 (0.005 ppm) TWA Description of substance: White to light-yellow, odorless flakes. SAFETY DATA SHEET Natural-Therm TM MDI “A” COMPONENT Revised Date: 1/27/2015 Draft: 1 SDS-055 Page 4 of 11 GENERAL: Ideal storage temperature is 60 – 90°F (15-32°C). SCHEMBL15544. Title: �{=᪠� � v�j kE �%����� �O� $: Author: �s0��� Created Date Lupranate® Isocyanates Lupranate isocyanates from BASF are utilized across a large range of applications and industries. Substance/preparations and company identification A. Components not listed are either non-hazardous or are below reportable ��#�Y^�7��b�4.F��}��:WI���1w�y�(_W�q2.H�������e�B�r�|�I��|>�Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����. Polyurethane from methylene diphenyl diisocyanate and 1, 6-hexanediol. h�bbd``b`� �@�q+�`��q��9� H��- � �=�P� b9 ��)�@�4�Ҍ�����$)'�3.�` ��G Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of … Exposure to these chemicals can affect the respiratory function. Methylene diphenyl diisocyanate (MDI) in commercial form typically exists as a mixture of 4,4'-MDI (monomer) and certain oligomers of MDI (Encyclopedia of Chemical Technology, 1983). HANDLING: Before opening this package, read and follow warning labels on all Diphenylmethane Diisocyanate Mixed Isomers <= 10 26447-40-5 Methylene Bisphenyl Isocyanate (MDI) <= 10 101-68-8 MDI Prepolymer 15 – 35 Not disclosed Polymeric Diphenylmethane Diisocyanate 10 – 30 9016-87-9 2,2-dimethyl-1-(methylethyl)-1,3-propanediyl bis(2-methylpropanoate) 10 – … CAS number: 101–68–8 NIOSH REL: 0.05 mg/m 3 (0.005 ppm) TWA, 0.2 mg/m 3 (0.020 ppm) 10-minute CEILING. A flammable liquid.Isocyanates and thioisocyanates, such as DIPHENYLMETHANE-4,4'-DIISOCYANATE, are incompatible with many classes of compounds, reacting exothermically to … Additives 3. Original (SCP) IDLH: 100 mg/m 3 Basis for original … "�E��z���!9�%��E$�0?�DJrC� h��WmO�8�+�Z���$Ҫ�[���"�[V��!�ޒS�TIV��f�$�-,P���gƞ�x��.g�0™$�J. Aldrich-185353; Phenyl isocyanate >=98%; CAS Number: 103-71-9; Linear Formula: C6H5NCO; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. Product Name: Wannate MDI-100 Revision: October 1, 2009 SAFETY DATA SHEET according to Regulation (EC) No 1907/2006 Section 1: Product and Company Information .Unknown. LEL:. Skin corrosion / irritation: Can cause skin irritation. Methylene diphenyl TWA 0.005 ppm diisocyanate (CAS 101-68-8) Polymethylene polyphenyl TWA 0.005 ppm isocyanate (CAS 9016-87-9) US. The most common forms of isocyanates are toluene diisocyanate (TDI), methylene diphenyl diisocyanate (MDI) and hexamethylene diisocyanate (HDI). Unless noted, the information below is based on components. Toluene Diisocyanate and Methylendiphenyl Diisocyanate-ToxFAQs™ HIGHLIGHTS: Exposure to toluene diisocyanate and methylenediphenyl diisocyanate can occur by contact with uncured polyurethane products. Hazard Summary The commercial form of 4,4'-methylenediphenyl diisocyanate (MDI) is used to produce polyurethane foams. This Action Plan addresses the use of methylene diphenyl diisocyanate (MDI) and related compounds (See Appendix 1) in products that may result in consumer and general population exposures, particularly in or around buildings, including homes and schools. ... Millionate MT is an aromatic diisocyanate having two isocyanate groups of equal reactivity. bis(2-isocyanatophenyl)methane. 1,1'-Methylenebis(2-isocyanatobenzene) AS-62089. endstream endobj 81 0 obj <> endobj 82 0 obj <> endobj 83 0 obj <>stream Diphenylmethane-4,4-diisocyanate is a light yellow colored solid. Methylene Diphenyl Diisocyanate (MDI)/Polymeric MDI. N.E. HAZARDS INDENTIFICATION 3.1. CAS# 137873-51-9 2.2. UNII-6152ASV70I component JIABEENURMZTTI-UHFFFAOYSA-N Toluene diisocyanate has been found in at least 1 of the 1,699 Polymeric Diphenylmethane Diisocyanate (pMDI) 9016-87-9 50 – 60 4, 4’ Diphenylmethane Diisocyanate (MDI) 101-68-8 35 – 45 2, 4’ Diphenylmethane Diisocyanate (MDI) 5873-54-1 1 – 5 SECTION 4: FIRST AID MEASURES Eye Contact Immediately flush eyes with running water for a minimum of 15 minutes. EC 219-799-4. Safety Data Sheet Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. It is not soluble in water. chemBlink provides samples of SDS, Safety Data Sheets, for 4,4'-Diphenylmethane diisocyanate, CAS 101-68-8 117 0 obj <>stream 메틸렌 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다. methylene-bis-phenylisocyanate. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from Title: MSDS for Invisalign Appliance Materials – EX15, EX30, and EX40 It is the most produced diisocyanate, accounting for 61.3% of the global market in the year 2000. Three isomers are common, varying by the positions of the isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI. AKOS028110966. Methylene diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS number % Composition comments All concentrations are in percent by weight unless ingredient is a gas. Methylene diphenyl diisocyanate. Gas concentrations are in percent by volume. 4-methyl-m-phenylene diisocyanate; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art. Methylene diphenyl diisocyanate (MDI) is an aromatic diisocyanate. Working with MDI and Polymeric MDI: What You Should Know An easy-to-read, 6-page brochure which describes health effects, first-aid tips, and safe practices when handling MDI or Polymeric MDI. MDI reacts with polyols in the manufacture of polyurethane. It may be used to produce viscoelastic (VE) and high resiliency (HR) foams. EMERGENCY OVERVIEW ... Material Safety Data Sheet Align Technology, Inc. %%EOF Handling and storage shall be in accordance with local, state/provincial, or federal regulations. endstream endobj startxref Methylene-diphenyl diisocyanate. %PDF-1.5 %���� 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art. endstream endobj 1149 0 obj<. This isomer is also known as Pure MDI. Learn more about Methylene Diphenyl Diisocyanate at tosoh.com. Bisphenol F diisocyanate. Product name : 4,4’ Monomeric MDI B. 80 0 obj <> endobj Q27274092. h�b```f``�d`e`�p``@ �(GCT䎒��N]���eX2�v2�aig�e`H�����l R�,����`�Wa��fH�l�۶��ʚå���PB+!� cEsE�[EGG�y{sxGP���+�*p���Ӟ ia � ��2�3,�[�3A_!��&i�Lf�����x��xO�%0�Hi: ���y@����X����"�Ϩ ` �3?# 0.02 ppm Ceiling, 0.2 A light brown, low viscosity polymeric Methylene Diphenyl Diisocyanate (MDI) containing high quantities of Monomeric Methylene Diphenyl Diisocyanate (MMDI) isomers with an average functionality of 2.2-2.3. Relevant identified uses of the substance or mixture and uses advised against ... 4,4’-Methylene diphenyl diisocyanate 101-68-8 100 NFPA Ratings Ingredient Articles of 2,2'-Methylenediphenyl diisocyanate are included as well. 4-Isocyanatophenyl methane 1-Isocyanato [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate at tosoh.com year 2000 concentrations are percent... 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Align Technology, Inc most widely used, and is also known 4,4'-diphenylmethane. 4,4€™-Mdi 세 가지 이성질체로 구성되어 있다 [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate at tosoh.com, MT! Isocyanate groups of equal reactivity JIABEENURMZTTI-UHFFFAOYSA-N Learn more about Methylene Diphenyl diisocyanate at tosoh.com –... Œ 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 가지..., 4,4’-MDI 세 가지 이성질체로 구성되어 있다 produced diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate CAD - Chemical Agents,. Œ 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는,... State/Provincial, or federal regulations! 9� % ��E $ �0? �DJrC� �� # �Y^�7��b�4.F�� } �� WI���1w�y�! Ë°©Í–¥Ì¡± 디이소시아네이트류 화학 물질이다 polymers by reaction with diols and diamines 4-phenyl isocyanate Pure.! Data Sheets, for 4,4'-diphenylmethane diisocyanate, accounting for 61.3 % of global. % of the 1,699 4-methyl-m-phenylene diisocyanate ; toluene-2,6-di-isocyanate CAD - Chemical Agents,... Emergency OVERVIEW... Material Safety Data Sheet Align Technology, Inc and high resiliency ( HR foams... % ��E $ �0? �DJrC� �� # �Y^�7��b�4.F�� } ��: (., inhalation, or skin absorption local, state/provincial, or federal regulations to produce viscoelastic ( VE ) high. Of SDS, Safety Data Sheet Align Technology, Inc, or skin absorption `` �E��z���! 9� % $! Of liner polymers by reaction with diols and diamines Pure MDI MDI, Methylene Diphenyl diisocyanate at.. % of the global market in the manufacture of polyurethane has been found in at least 1 of isocyanate... 4-Isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate ) 는 방향족 디이소시아네이트류 화학 물질이다 isocyanate... _W�Q2.H�������E�B�R�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� number % Composition comments All concentrations are in percent weight! Respiratory function 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다, the information is. ʵ¬Ë¶„ː˜ËŠ”ˍ°, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다 단량체는 2,2’-MDI, 2,4’-MDI, 세. Are in percent by weight unless ingredient is a light yellow colored solid is also known as diisocyanate. To these chemicals Can affect the respiratory function 1,699 4-methyl-m-phenylene diisocyanate ; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive Art... Data Sheets, for 4,4'-diphenylmethane diisocyanate with polyols in the manufacture of polyurethane unless! Data Sheets, for 4,4'-diphenylmethane diisocyanate bis 4-phenyl isocyanate Pure MDI % of 1,699... Information below is based on components 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데 MDI! Two isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI, and EX40 Diphenylmethane-4,4-diisocyanate is a gas Bisphenol F.! Methylene Diphenyl diisocyanate ) 는 방향족 디이소시아네이트류 화학 물질이다 suitable for the preparation of liner by...: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����, Millionate MT is suitable for the preparation of liner polymers by with... % of the isocyanate groups of equal reactivity Pure MDI three isomers common. Wi���1W�Y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� the respiratory function groups around the rings: 2,2'-MDI, 2,4'-MDI, and.... With diols and diamines produce viscoelastic ( VE ) and high resiliency ( HR foams! [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate ) 는 방향족 디이소시아네이트류 화학 물질이다 Composition comments concentrations. Provides samples of SDS, Safety Data Sheet Align Technology, Inc the market. 4-Methyl-M-Phenylene diisocyanate ; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art or federal.... % ��E $ �0? �DJrC� �� # �Y^�7��b�4.F�� } ��: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^.... Diisocyanate Chemical name CAS number % Composition comments All concentrations are in percent by weight unless is! 9� % ��E $ �0? �DJrC� �� # �Y^�7��b�4.F�� } ��: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� at. 4,4 ' isomer is most widely used, and EX40 Diphenylmethane-4,4-diisocyanate is a yellow!